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KMID : 1059519850290040414
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Journal of the Korean Chemical Society
1985 Volume.29 No. 4 p.414 ~ p.418
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Oxidative Rearrangement of Tertiary Allylic Alcohols
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Kim In-Kyu
Oh Chang-Sok
Hong Young-Tech
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Abstract
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A general synthesis of α,β-unsaturated carbonyl compounds has been developed by oxidation of t-allylic alcohols. In simpler system, pyridinium chlorochromate oxidation affords the functionality transposed carbonyls in excellent yields, making the reaction a useful and versatile synthetic method.
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